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Creators/Authors contains: "Awais, Mohammad Ahmad"

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  1. ; ; ; ; ; ; ; ; (, ACS Applied Energy Materials)
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  2. ; ; ; ; ; (, Journal of Materials Chemistry C)
    A photoinduced cationic polycondensation towards the synthesis of a thieno[3,4- b ]thiophene (TT) based homopolymer PTT-L was described. The reaction mechanism was investigated by employing a series of control experiments. It was found that the polymerization initiated with a light-induced radical formation, followed by a cationic propagation, all in solid state, at room temperature, and without any catalyst or solvent. In addition, a reference polymer ( PTT-Ni ) was synthesized via Kumada catalyst transfer polycondensation (KCTP) to assist in structural characterization of polymer PTT-L . It was shown that both polymers exhibit analogous optical, thermal, electrochemical and electrical properties. This polymerization process can be utilized as a mean to form patterned PTT-L films. 
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